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TitleCatalytic Promiscuity of Transaminases: Preparation of Enantioenriched Beta-Fluoroamines by Formal Tandem Hydrodefluorination/Deamination.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 55, Page 3144-, Year 2016
Publish dateDec 16, 2015 (structure data deposition date)
AuthorsCuetos, A. / Garcia-Ramos, M. / Fischereder, E. / Diaz-Rodriguez, A. / Grogan, G. / Gotor, V. / Kroutil, W. / Lavandera, I.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:26836037
MethodsX-ray diffraction
Resolution2.81 Å
Structure data

PDB-5fr9:
Structure of transaminase ATA-117 arRmut11 from Arthrobacter sp. KNK168 inhibited with 1-(4-Bromophenyl)-2-fluoroethylamine
Method: X-RAY DIFFRACTION / Resolution: 2.81 Å

Chemicals

ChemComp-9HC:
[4-[3-(4-bromophenyl)-3-oxidanylidene-propyl]-6-methyl-5-oxidanyl-pyridin-3-yl]methyl phosphate

ChemComp-HOH:
WATER

Source
  • arthrobacter sp. (bacteria)
KeywordsTRANSFERASE / TRANSMINASE / AMINOTRANSFERASE / PLP / INHIBITOR / FLUOROAMINE

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