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TitleExtremely elevated room-temperature kinetic isotope effects quantify the critical role of barrier width in enzymatic C-H activation.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 136, Page 8157-8160, Year 2014
Publish dateSep 21, 2014 (structure data deposition date)
AuthorsHu, S. / Sharma, S.C. / Scouras, A.D. / Soudackov, A.V. / Carr, C.A. / Hammes-Schiffer, S. / Alber, T. / Klinman, J.P.
External linksJ. Am. Chem. Soc. / PubMed:24884374
MethodsX-ray diffraction
Resolution1.7 Å
Structure data

PDB-4wha:
Lipoxygenase-1 (soybean) L546A/L754A mutant
Method: X-RAY DIFFRACTION / Resolution: 1.7 Å

Chemicals

ChemComp-FE:
Unknown entry

ChemComp-EDO:
1,2-ETHANEDIOL

ChemComp-ACT:
ACETATE ION

ChemComp-HOH:
WATER

Source
  • glycine max (soybean)
KeywordsOXIDOREDUCTASE / lipoxygenase / tunneling / C-H activation

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