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TitleTheoretical and experimental studies of the conversion of chromopyrrolic acid to an antitumor derivative by cytochrome P450 StaP: the catalytic role of water molecules
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 131, Page 6748-6762, Year 2009
Publish dateApr 9, 2009 (structure data deposition date)
AuthorsWang, Y. / Chen, H. / Makino, M. / Shiro, Y. / Nagano, S. / Asamizu, S. / Onaka, H. / Shaik, S.
External linksJ. Am. Chem. Soc. / PubMed:19385626
MethodsX-ray diffraction
Resolution2.5 Å
Structure data

PDB-3a1l:
Crystal Structure of 11,11'-Dichlorochromopyrrolic Acid Bound Cytochrome P450 StaP (CYP245A1)
Method: X-RAY DIFFRACTION / Resolution: 2.5 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-2CC:
3,4-bis(7-chloro-1H-indol-3-yl)-1H-pyrrole-2,5-dicarboxylic acid

ChemComp-HOH:
WATER

Source
  • streptomyces sp. tp-a0274 (bacteria)
KeywordsOXIDOREDUCTASE / cytochrome P450 / monooxygenase / heme-enzyme / Heme / Iron / Metal-binding

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