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Structure paper

TitleCatalysis at a dinuclear [CuSMo(=O)OH] cluster in a CO dehydrogenase resolved at 1.1-A resolution
Journal, issue, pagesProc. Natl. Acad. Sci. USA, Vol. 99, Page 15971-15976, Year 2002
Publish dateNov 7, 2002 (structure data deposition date)
AuthorsDobbek, H. / Gremer, L. / Kiefersauer, R. / Huber, R. / Meyer, O.
External linksProc. Natl. Acad. Sci. USA / PubMed:12475995
MethodsX-ray diffraction
Resolution1.09 - 1.5 Å
Structure data

PDB-1n5w:
Crystal Structure of the Cu,Mo-CO Dehydrogenase (CODH); Oxidized form
Method: X-RAY DIFFRACTION / Resolution: 1.5 Å

PDB-1n60:
Crystal Structure of the Cu,Mo-CO Dehydrogenase (CODH); Cyanide-inactivated Form
Method: X-RAY DIFFRACTION / Resolution: 1.19 Å

PDB-1n61:
Crystal Structure of the Cu,Mo-CO Dehydrogenase (CODH); Dithionite reduced state
Method: X-RAY DIFFRACTION / Resolution: 1.3 Å

PDB-1n62:
Crystal Structure of the Mo,Cu-CO Dehydrogenase (CODH), n-butylisocyanide-bound state
Method: X-RAY DIFFRACTION / Resolution: 1.09 Å

PDB-1n63:
Crystal Structure of the Cu,Mo-CO Dehydrogenase (CODH); Carbon monoxide reduced state
Method: X-RAY DIFFRACTION / Resolution: 1.21 Å

Chemicals

ChemComp-PO4:
PHOSPHATE ION

ChemComp-FES:
FE2/S2 (INORGANIC) CLUSTER

ChemComp-CUM:
CU(I)-S-MO(VI)(=O)OH CLUSTER

ChemComp-MCN:
PTERIN CYTOSINE DINUCLEOTIDE

ChemComp-FAD:
FLAVIN-ADENINE DINUCLEOTIDE / FAD*YM

ChemComp-HOH:
WATER

ChemComp-OMO:
MO(VI)(=O)(OH)2 CLUSTER

ChemComp-CUN:
CU(I)-S-MO(IV)(=O)OH CLUSTER

ChemComp-CUB:
CU(I)-S-MO(IV)(=O)O-NBIC CLUSTER

Source
  • oligotropha carboxidovorans (bacteria)
KeywordsOXIDOREDUCTASE / molybdopterin / molybdenum / MCD / CODH

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