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TitleBiosynthesis of the Thiofuranose Core in Albomycin Requires a Versatile Enzyme AbmG That Catalyzes Net Dehydration via Cryptic Phosphorylation
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 147, Page 34143-34149, Year 2025
Publish dateApr 22, 2023 (structure data deposition date)
AuthorsZheng, Z. / Ushimaru, R. / Mori, T. / Ruszczycky, M.W. / Abe, I. / Liu, H.W.
External linksJ. Am. Chem. Soc. / Search PubMed
MethodsX-ray diffraction
Resolution1.4 - 1.7 Å
Structure data

PDB-8j5e:
Crystal structure of kinase AbmG in complex with 4'-thiocytidine
Method: X-RAY DIFFRACTION / Resolution: 1.7 Å

PDB-8j5f:
Crystal structure of kinase AbmG in complex with cytidine and ADP
Method: X-RAY DIFFRACTION / Resolution: 1.7 Å

PDB-8j5g:
Crystal structure of kinase AbmG in complex with 4'-hydroxy-4'-thiocytidine 5'-diphosphate
Method: X-RAY DIFFRACTION / Resolution: 1.5 Å

PDB-8j5h:
Crystal structure of kinase AbmG in complex with 4'-hydroxy-4'-thiocytidine
Method: X-RAY DIFFRACTION / Resolution: 1.4 Å

Chemicals


ChemComp, No image

ChemComp-TQR:
Unknown entry

ChemComp-HOH:
WATER

ChemComp-CTN:
4-AMINO-1-BETA-D-RIBOFURANOSYL-2(1H)-PYRIMIDINONE

ChemComp-ADP:
ADENOSINE-5'-DIPHOSPHATE / ADP, energy-carrying molecule*YM


ChemComp, No image

ChemComp-TT9:
Unknown entry


ChemComp, No image

ChemComp-TV0:
Unknown entry

ChemComp-NO3:
NITRATE ION

Source
  • streptomyces sp. atcc 700974 (bacteria)
KeywordsTRANSFERASE / Albomycin / biosynthesis

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