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TitleStructure and Mechanism of the Pyridoxal 5'-Phosphate-Dependent Amino Acid gamma-Substitution Enzyme in 6-Alkyl-Pipecolate Biosynthesis
Journal, issue, pagesAcs Catalysis, Page 18893-18907, Year 2025
Publish dateMay 13, 2024 (structure data deposition date)
AuthorsGao, Y. / Wang, B. / Zhou, J. / Gu, Y.
External linksAcs Catalysis / Search PubMed
MethodsX-ray diffraction
Resolution2.59 - 2.95 Å
Structure data

PDB-8zif:
Gamma-lyase CndF in complex with pyridoxal 5'-phosphate, L-homoserine and ethyl acetoacetate
Method: X-RAY DIFFRACTION / Resolution: 2.95 Å

PDB-8zij:
The holo structure of gamma-lyase CndF
Method: X-RAY DIFFRACTION / Resolution: 2.59 Å

PDB-8zil:
Gamma-lyase CndF in complex with ethyl acetoacetate
Method: X-RAY DIFFRACTION / Resolution: 2.65 Å

Chemicals

ChemComp-HSE:
L-HOMOSERINE

ChemComp-EAC:
ethyl 3-oxobutanoate

ChemComp-PO4:
PHOSPHATE ION

ChemComp-CL:
Unknown entry

ChemComp-HOH:
WATER

Source
  • penicillium citrinum (fungus)
KeywordsLYASE / PLP dependent / Gamma-lyase / C-C bond formation

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